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Ozone | Definition, Properties, Structure, & Facts | Britannica
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Also known as: O3
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ozone, (O3), triatomic allotrope of oxygen (a form of oxygen in which the molecule contains three atoms instead of two as in the common form) that accounts for the distinctive odour of the air after a thunderstorm or around electrical equipment. The odour of ozone around electrical machines was reported as early as 1785; ozone’s chemical constitution was established in 1872. Ozone is an irritating pale blue gas that is explosive and toxic, even at low concentrations. It occurs naturally in small amounts in Earth’s stratosphere, where it absorbs solar ultraviolet radiation, which otherwise could cause severe damage to living organisms on Earth’s surface. Under certain conditions, photochemical reactions between nitrogen oxides and hydrocarbons in the lower atmosphere can produce ozone in concentrations high enough to cause irritation of the eyes and mucous membranes.Ozone usually is manufactured by passing an electric discharge through a current of oxygen or dry air. The resulting mixtures of ozone and original gases are suitable for most industrial purposes, although purer ozone may be obtained from them by various methods; for example, upon liquefaction, an oxygen-ozone mixture separates into two layers, of which the denser one contains about 75 percent ozone. The extreme instability and reactivity of concentrated ozone makes its preparation both difficult and hazardous.
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global warming: Surface-level ozone and other compounds
Ozone is 1.5 times as dense as oxygen; at −112 °C (−170 °F) it condenses to a dark blue liquid, which freezes at −251.4 °C (−420 °F). The gas decomposes rapidly at temperatures above 100 °C (212 °F) or, in the presence of certain catalysts, at room temperatures. Although it resembles oxygen in many respects, ozone is much more reactive; hence, it is an extremely powerful oxidizing agent, particularly useful in converting olefins into aldehydes, ketones, or carboxylic acids. Because it can decolorize many substances, it is used commercially as a bleaching agent for organic compounds; as a strong germicide it is used to sterilize drinking water as well as to remove objectionable odours and flavours. See also ozonosphere. The Editors of Encyclopaedia BritannicaThis article was most recently revised and updated by Adam Augustyn.
Ozone layer | Description, Importance, & Facts | Britannica
Ozone layer | Description, Importance, & Facts | Britannica
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ozone layer
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ozone layer
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IntroductionLocation in Earth’s atmosphereOzone creation and destruction
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Also known as: ozonosphere
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Harry E. Preble Professor of Atmospheric Sciences, Department of Atmospheric Sciences, University of Illinois, Urbana, Illinois.
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layers of Earth's atmosphere
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ozone layer, region of the upper atmosphere, between roughly 15 and 35 km (9 and 22 miles) above Earth’s surface, containing relatively high concentrations of ozone molecules (O3). Approximately 90 percent of the atmosphere’s ozone occurs in the stratosphere, the region extending from 10–18 km (6–11 miles) to approximately 50 km (about 30 miles) above Earth’s surface. In the stratosphere the temperature of the atmosphere rises with increasing height, a phenomenon created by the absorption of solar radiation by the ozone layer. The ozone layer effectively blocks almost all solar radiation of wavelengths less than 290 nm from reaching Earth’s surface, including certain types of ultraviolet (UV) and other forms of radiation that could injure or kill most living things. Location in Earth’s atmosphere In the midlatitudes the peak concentrations of ozone occur at altitudes from 20 to 25 km (about 12 to 16 miles). Peak concentrations are found at altitudes from 26 to 28 km (about 16 to 17 miles) in the tropics and from about 12 to 20 km (about 7 to 12 miles) toward the poles. The lower height of the peak-concentration region in the high latitudes largely results from poleward and downward atmospheric transport processes that occur in the middle and high latitudes and the reduced height of the tropopause (the transition region between the troposphere and stratosphere). ozone damage on leafOzone damage on the leaf of an English walnut (Juglans regia).(more)Most of the remaining ozone occurs in the troposphere, the layer of the atmosphere that extends from Earth’s surface up to the stratosphere. Near-surface ozone often results from interactions between certain pollutants (such as nitrogen oxides and volatile organic compounds), strong sunlight, and hot weather. It is one of the primary ingredients in photochemical smog, a phenomenon that plagues many urban and suburban areas around the world, especially during the summer months. Ozone creation and destruction ozone: holeChanges in the size of the ozone hole from October 1979 to October 1990.(more)The production of ozone in the stratosphere results primarily from the breaking of the chemical bonds within oxygen molecules (O2) by high-energy solar photons. This process, called photodissociation, results in the release of single oxygen atoms, which later join with intact oxygen molecules to form ozone. Rising atmospheric oxygen concentrations some two billion years ago allowed ozone to build up in Earth’s atmosphere, a process that gradually led to the formation of the stratosphere. Scientists believe that the formation of the ozone layer played an important role in the development of life on Earth by screening out lethal levels of UVB radiation (ultraviolet radiation with wavelengths between 315 and 280 nm) and thus facilitating the migration of life-forms from the oceans to land. ozone depletionAntarctic ozone hole, September 17, 2001.(more)The amount of ozone in the stratosphere varies naturally throughout the year as a result of chemical processes that create and destroy ozone molecules and as a result of winds and other transport processes that move ozone molecules around the planet. Over the course of several decades, however, human activities substantially altered the ozone layer. Ozone depletion, the global decrease in stratospheric ozone observed since the 1970s, is most pronounced in polar regions, and it is well correlated with the increase of chlorine and bromine in the stratosphere. Those chemicals, once freed by UV radiation from the chlorofluorocarbons (CFCs) and other halocarbons (carbon-halogen compounds) that contain them, destroy ozone by stripping away single oxygen atoms from ozone molecules. Depletion is so extensive that so-called ozone holes (regions of severely reduced ozone coverage) form over the poles during the onset of their respective spring seasons. The largest such hole—which has spanned more than 20.7 million square km (8 million square miles) on a consistent basis since 1992—appears annually over Antarctica between September and November.
ozonesondeResearchers launching a balloon carrying an ozonesonde, an instrument that measures ozone in the atmosphere, at Amundsen-Scott South Pole Station in Antarctica. (more)As the amount of stratospheric ozone declines, more UV radiation reaches Earth’s surface, and scientists worry that such increases could have significant effects on ecosystems and human health. The concern over exposure to biologically harmful levels of UV radiation has been the main driver of the creation of international treaties such as the Montreal Protocol on Substances That Deplete the Ozone Layer and its amendments, designed to protect Earth’s ozone layer. The Montreal Protocol has been a success: some 99 percent of the ozone-depleting chemicals regulated by the treaty have been phased out since its adoption in 1987. Compliance with international treaties that phased out the production and delivery of many ozone-depleting chemicals, combined with upper stratospheric cooling due to increased carbon dioxide, is thought to have contributed to the shrinking of the ozone holes over the poles and to slightly higher stratospheric ozone levels overall. Studies note that continued reductions in ozone-depleting chemicals that follow the schedule proposed by the Montreal Protocol and its follow-up agreements are expected to result in a return to 1980-level ozone concentrations above the poles by as early as 2040, with the closure of the ozone holes above Antarctica by about 2066 and above the Arctic by about 2045.
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Ozone depletion | Facts, Effects, & Solutions | Britannica
Ozone depletion | Facts, Effects, & Solutions | Britannica
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ozone depletion
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ozone depletion
Table of Contents
IntroductionHistoryAntarctic ozone holeOzone layer recovery
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Pop Quiz: 18 Things to Know About Global Warming
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Also known as: ozone hole
Written by
Donald Wuebbles
Harry E. Preble Professor of Atmospheric Sciences, Department of Atmospheric Sciences, University of Illinois, Urbana, Illinois.
Donald Wuebbles
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ozone depletion
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Joseph C. Farman
Mario Molina
F. Sherwood Rowland
Paul Crutzen
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ozone depletion, gradual thinning of Earth’s ozone layer in the upper atmosphere caused by the release of chemical compounds containing gaseous chlorine or bromine from industry and other human activities. The thinning is most pronounced in the polar regions, especially over Antarctica. Ozone depletion is a major environmental problem because it increases the amount of ultraviolet (UV) radiation that reaches Earth’s surface, which increases the rate of skin cancer, eye cataracts, and genetic and immune system damage. The Montreal Protocol, ratified in 1987, was the first of several comprehensive international agreements enacted to halt the production and use of ozone-depleting chemicals. As a result of continued international cooperation on this issue, the ozone layer is expected to recover over time. History In 1969 Dutch chemist Paul Crutzen published a paper that described the major nitrogen oxide catalytic cycle affecting ozone levels. Crutzen demonstrated that nitrogen oxides can react with free oxygen atoms, thus slowing the creation of ozone (O3), and can also decompose ozone into nitrogen dioxide (NO2) and oxygen gas (O2). Some scientists and environmentalists in the 1970s used Crutzen’s research to assist their argument against the creation of a fleet of American supersonic transports (SSTs). They feared that the potential emission of nitrogen oxides and water vapour from these aircraft would damage the ozone layer. (SSTs were designed to fly at altitudes coincident with the ozone layer, some 15 to 35 km [9 to 22 miles] above Earth’s surface.) In reality, the American SST program was canceled, and only a small number of French-British Concordes and Soviet Tu-144s went into service, so that the effects of SSTs on the ozone layer were found to be negligible for the number of aircraft in operation. In 1974, however, American chemists Mario Molina and F. Sherwood Rowland of the University of California at Irvine recognized that human-produced chlorofluorocarbons (CFCs)—molecules containing only carbon, fluorine, and chlorine atoms—could be a major source of chlorine in the stratosphere. They also noted that chlorine could destroy extensive amounts of ozone after it was liberated from CFCs by UV radiation. Free chlorine atoms and chlorine-containing gases, such as chlorine monoxide (ClO), could then break ozone molecules apart by stripping away one of the three oxygen atoms. Later research revealed that bromine and certain bromine-containing compounds, such as bromine monoxide (BrO), were even more effective at destroying ozone than were chlorine and its reactive compounds. Subsequent laboratory measurements, atmospheric measurements, and atmospheric-modeling studies soon substantiated the importance of their findings. Crutzen, Molina, and Rowland received the Nobel Prize for Chemistry in 1995 for their efforts. ozonesondeResearchers launching a balloon carrying an ozonesonde, an instrument that measures ozone in the atmosphere, at Amundsen-Scott South Pole Station in Antarctica. (more)Human activities have had a significant effect on the global concentration and distribution of stratospheric ozone since before the 1980s. In addition, scientists have noted that large annual decreases in average ozone concentrations began to occur by at least 1980. Measurements from satellites, aircraft, ground-based sensors, and other instruments indicate that total integrated column levels of ozone (that is, the number of ozone molecules occurring per square metre in sampled columns of air) decreased globally by roughly 5 percent between 1970 and the mid-1990s, with little change afterward. The largest decreases in ozone took place in the high latitudes (toward the poles), and the smallest decreases occurred in the lower latitudes (the tropics). In addition, atmospheric measurements show that the depletion of the ozone layer increased the amount of UV radiation reaching Earth’s surface.
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ozone depletion processA flowchart depicting the principal steps in the depletion of stratospheric ozone.(more)ozone depletion's connection to mass extinctionAn experiment showing how pine trees become temporarily sterile when exposed to intense UV radiation, supporting the theory that ozone depletion may have caused Earth's largest mass extinction.(more)See all videos for this articleThis global decrease in stratospheric ozone is well correlated with rising levels of chlorine and bromine in the stratosphere from the manufacture and release of CFCs and other halocarbons. Halocarbons are produced by industry for a variety of uses, such as refrigerants (in refrigerators, air conditioners, and large chillers), propellants for aerosol cans, blowing agents for making plastic foams, firefighting agents, and solvents for dry cleaning and degreasing. Atmospheric measurements have clearly corroborated theoretical studies showing that chlorine and bromine released from halocarbons in the stratosphere react with and destroy ozone. Antarctic ozone hole The most severe case of ozone depletion was first documented in 1985 in a paper by British Antarctic Survey (BAS) scientists Joseph C. Farman, Brian G. Gardiner, and Jonathan D. Shanklin. Beginning in the late 1970s, a large and rapid decrease in total ozone, often by more than 60 percent relative to the global average, has been observed in the springtime (September to November) over Antarctica. Farman and his colleagues first documented this phenomenon over their BAS station at Halley Bay, Antarctica. Their analyses attracted the attention of the scientific community, which found that these decreases in the total ozone column were greater than 50 percent compared with historical values observed by both ground-based and satellite techniques.
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As a result of the Farman paper, a number of hypotheses arose that attempted to explain the Antarctic “ozone hole.” It was initially proposed that the ozone decrease might be explained by the chlorine catalytic cycle, in which single chlorine atoms and their compounds strip single oxygen atoms from ozone molecules. Since more ozone loss occurred than could be explained by the supply of reactive chlorine available in the polar regions by known processes at that time, other hypotheses arose. A special measurement campaign conducted by the National Aeronautics and Space Administration (NASA) and the National Oceanic and Atmospheric Administration (NOAA) in 1987, as well as later measurements, proved that chlorine and bromine chemistry were indeed responsible for the ozone hole, but for another reason: the hole appeared to be the product of chemical reactions occurring on particles that make up polar stratospheric clouds (PSCs) in the lower stratosphere. During the winter the air over the Antarctic becomes extremely cold as a result of the lack of sunlight and a reduced mixing of lower stratospheric air over Antarctica with air outside the region. This reduced mixing is caused by the circumpolar vortex, also called the polar winter vortex. Bounded by a stratospheric jet of wind circulating between approximately 50° and 65° S, the air over Antarctica and its adjacent seas is effectively isolated from air outside the region. The extremely cold temperatures inside the vortex lead to the formation of PSCs, which occur at altitudes of roughly 12 to 22 km (about 7 to 14 miles). Chemical reactions that take place on PSC particles convert less-reactive chlorine-containing molecules to more-reactive forms such as molecular chlorine (Cl2) that accumulate during the polar night. (Bromine compounds and nitrogen oxides can also react with these cloud particles.) When day returns to Antarctica in the early spring, sunlight breaks the molecular chlorine into single chlorine atoms that can react with and destroy ozone. Ozone destruction continues until the breakup of the polar vortex, which usually takes place in November.
A polar winter vortex also forms in the Northern Hemisphere. However, in general, it is neither as strong nor as cold as the one that forms in the Antarctic. Although polar stratospheric clouds can form in the Arctic, they rarely last long enough for extensive decreases in ozone. Arctic ozone decreases of as much as 40 percent have been measured. This thinning typically occurs during years when lower-stratospheric temperatures in the Arctic vortex have been sufficiently low to lead to ozone-destruction processes similar to those found in the Antarctic ozone hole. As with Antarctica, large increases in concentrations in reactive chlorine have been measured in Arctic regions where high levels of ozone destruction occur.
Ozone depletion, ultraviolet radiation, climate change and prospects for a sustainable future | Nature Sustainability
Ozone depletion, ultraviolet radiation, climate change and prospects for a sustainable future | Nature Sustainability
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Review Article
Published: 24 June 2019
Ozone depletion, ultraviolet radiation, climate change and prospects for a sustainable future
Paul W. Barnes
ORCID: orcid.org/0000-0002-5715-36791 na1, Craig E. Williamson2 na1, Robyn M. Lucas
ORCID: orcid.org/0000-0003-2736-35413 na1, Sharon A. Robinson
ORCID: orcid.org/0000-0002-7130-96174 na1, Sasha Madronich5 na1, Nigel D. Paul6 na1, Janet F. Bornman7, Alkiviadis F. Bais8, Barbara Sulzberger9, Stephen R. Wilson10, Anthony L. Andrady11, Richard L. McKenzie12, Patrick J. Neale13, Amy T. Austin14, Germar H. Bernhard15, Keith R. Solomon
ORCID: orcid.org/0000-0002-8496-641316, Rachel E. Neale17, Paul J. Young6, Mary Norval18, Lesley E. Rhodes19, Samuel Hylander20, Kevin C. Rose21, Janice Longstreth22, Pieter J. Aucamp23, Carlos L. Ballaré14, Rose M. Cory24, Stephan D. Flint25, Frank R. de Gruijl26, Donat-P. Häder27, Anu M. Heikkilä28, Marcel A. K. Jansen29, Krishna K. Pandey30, T. Matthew Robson31, Craig A. Sinclair32, Sten-Åke Wängberg33, Robert C. Worrest34, Seyhan Yazar35, Antony R. Young36 & …Richard G. Zepp37 Show authors
Nature Sustainability
volume 2, pages 569–579 (2019)Cite this article
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AbstractChanges in stratospheric ozone and climate over the past 40-plus years have altered the solar ultraviolet (UV) radiation conditions at the Earth’s surface. Ozone depletion has also contributed to climate change across the Southern Hemisphere. These changes are interacting in complex ways to affect human health, food and water security, and ecosystem services. Many adverse effects of high UV exposure have been avoided thanks to the Montreal Protocol with its Amendments and Adjustments, which have effectively controlled the production and use of ozone-depleting substances. This international treaty has also played an important role in mitigating climate change. Climate change is modifying UV exposure and affecting how people and ecosystems respond to UV; these effects will become more pronounced in the future. The interactions between stratospheric ozone, climate and UV radiation will therefore shift over time; however, the Montreal Protocol will continue to have far-reaching benefits for human well-being and environmental sustainability.
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Fig. 1: The Sustainable Development Goals (SDGs) addressed by the UNEP Environmental Effects Assessment Panel 2018 Quadrennial Report.Fig. 2: Links between stratospheric ozone depletion, UV radiation and climate change.
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This paper has been reviewed in accordance with the US Environmental Protection Agency’s (US EPA) peer and administrative review policies and approved for publication. Mention of trade names or commercial products does not constitute an endorsement or recommendation for use by the US EPA.Author informationAuthor notesThese authors contributed equally: Paul W. Barnes, Craig E. Williamson, Robyn M. Lucas, Sharon A. Robinson, Sasha Madronich, Nigel D. Paul.Authors and AffiliationsDepartment of Biological Sciences and Environment Program, Loyola University New Orleans, New Orleans, LA, USAPaul W. BarnesDepartment of Biology, Miami University, Oxford, OH, USACraig E. WilliamsonNational Centre for Epidemiology and Population Health, The Australian National University, Canberra, AustraliaRobyn M. LucasCentre for Sustainable Ecosystem Solutions, School of Earth, Atmosphere and Life Sciences & Global Challenges Program, University of Wollongong, Wollongong, New South Wales, AustraliaSharon A. RobinsonNational Center for Atmospheric Research, Boulder, CO, USASasha MadronichLancaster Environment Centre, Lancaster University, Lancaster, UKNigel D. Paul & Paul J. YoungFood Futures Institute, Murdoch University, Perth, Western Australia, AustraliaJanet F. BornmanLaboratory of Atmospheric Physics, Aristotle University of Thessaloniki, Thessaloniki, GreeceAlkiviadis F. BaisSwiss Federal Institute of Aquatic Science and Technology (Eawag), Dübendorf, SwitzerlandBarbara SulzbergerCentre for Atmospheric Chemistry, School of Earth, Atmosphere and Life Sciences, University of Wollongong, Wollongong, New South Wales, AustraliaStephen R. WilsonDepartment of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh, NC, USAAnthony L. AndradyNational Institute of Water and Atmospheric Research, Central Otago, New ZealandRichard L. McKenzieSmithsonian Environmental Research Center, Edgewater, MD, USAPatrick J. NealeFaculty of Agronomy and IFEVA-CONICET, University of Buenos Aires, Buenos Aires, ArgentinaAmy T. Austin & Carlos L. BallaréBiospherical Instruments Inc., San Diego, CA, USAGermar H. BernhardSchool of Environmental Sciences, University of Guelph, Guelph, Ontario, CanadaKeith R. SolomonQIMR Berghofer Medical Research Institute, Herston, Queensland, AustraliaRachel E. NealeBiomedical Sciences, University of Edinburgh Medical School, Edinburgh, UKMary NorvalCentre for Dermatology Research, The University of Manchester and Salford Royal NHS Foundation Trust, Manchester, UKLesley E. RhodesCentre for Ecology and Evolution in Microbial Model Systems, Linnaeus University, Kalmar, SwedenSamuel HylanderDepartment of Biological Sciences, Rensselaer Polytechnic Institute, Troy, NY, USAKevin C. RoseThe Institute for Global Risk Research, Bethesda, MD, USAJanice LongstrethPtersa Environmental Consultants, Faerie Glen, South AfricaPieter J. AucampDepartment of Earth and Environmental Sciences, University of Michigan, Ann Arbor, MI, USARose M. CoryDepartment of Forest, Rangeland, and Fire Sciences, University of Idaho, Moscow, ID, USAStephan D. FlintDepartment of Dermatology, Leiden University Medical Centre, Leiden, The NetherlandsFrank R. de GruijlFriedrich-Alexander University, Erlangen-Nürnberg, GermanyDonat-P. HäderFinnish Meteorological Institute R&D/Climate Research, Helsinki, FinlandAnu M. HeikkiläSchool of Biological, Earth and Environmental Sciences, University College Cork, Cork, IrelandMarcel A. K. JansenInstitute of Wood Science and Technology, Bengaluru, IndiaKrishna K. PandeyOrganismal and Evolutionary Biology, Vikki Plant Science Centre, University of Helsinki, Helsinki, FinlandT. Matthew RobsonCancer Council Victoria, Melbourne, AustraliaCraig A. SinclairDepartment of Marine Sciences, University of Gothenburg, Göteborg, SwedenSten-Åke WängbergCIESIN, Columbia University, New Hartford, CT, USARobert C. WorrestCentre for Ophthalmology and Visual Science, University of Western Australia, Perth, Western Australia, AustraliaSeyhan YazarSt. John’s Institute of Dermatology, King’s College London, London, UKAntony R. YoungUS Environmental Protection Agency, Athens, GA, USARichard G. ZeppAuthorsPaul W. BarnesView author publicationsYou can also search for this author in
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PubMed Google ScholarContributionsAll authors helped in the development and review of this paper. The lead authors P.W.B., C.E.W., R.M.L., S.A.R., S.M. and N.D.P. played major roles in conceptualizing and writing the document. P.W.B. organized and coordinated the paper and integrated comments and revisions on all the drafts. C.E.W., R.M.L., J.F.B., A.F.B., B.S., S.R.W. and A.L.A. provided content with the assistance of S.M., S.A.R., G.H.B., R.L.M., P.J.A., A.M.H., P.J.Y. (stratospheric ozone effects on UV and ozone-driven climate change), R.E.N., F.R.deG., M.N., L.E.R., C.A.S., S.Y., A.R.Y. (human health), P.W.B., S.A.R., C.L.B., S.D.F., M.A.K.J., T.M.R. (agriculture and terrestrial ecosystems), P.J.N., S.H., K.C.R., R.M.C., D.-P.H., S-Å.W., R.C.W. (fisheries and aquatic ecosystems), A.T.A., R.G.Z. (biogeochemistry and contaminants), K.R.S., J.L. (air quality and toxicology) and K.K.P. (materials). R.L.M. conducted the UV simulation modelling.Corresponding authorCorrespondence to
Paul W. Barnes.Ethics declarations
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The authors declare no competing interests.
Additional informationPublisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.Rights and permissionsReprints and permissionsAbout this articleCite this articleBarnes, P.W., Williamson, C.E., Lucas, R.M. et al. Ozone depletion, ultraviolet radiation, climate change and prospects for a sustainable future.
Nat Sustain 2, 569–579 (2019). https://doi.org/10.1038/s41893-019-0314-2Download citationReceived: 23 October 2018Accepted: 16 May 2019Published: 24 June 2019Issue Date: July 2019DOI: https://doi.org/10.1038/s41893-019-0314-2Share this articleAnyone you share the following link with will be able to read this content:Get shareable linkSorry, a shareable link is not currently available for this article.Copy to clipboard
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OZONE中文(简体)翻译:剑桥词典
OZONE中文(简体)翻译:剑桥词典
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英语-中文(简体)
ozone 在英语-中文(简体)词典中的翻译
ozonenoun [ U ] uk
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/ˈəʊ.zəʊn/ us
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/ˈoʊ.zoʊn/
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C1 a poisonous form of oxygen
臭氧
UK informal air that is clean and pleasant to breathe, especially near the sea
(尤指海边的)新鲜空气
(ozone在剑桥英语-中文(简体)词典的翻译 © Cambridge University Press)
ozone的例句
ozone
There are four widely recognized drivers of this degradation of the biosphere: climate change, ozone depletion, toxic chemicals, and habitat destruction.
来自 Cambridge English Corpus
Here, alongside the elixir of ozone and holiday remembrances, there exists an enticing picture of crime-free boulevards and peer-group sociability.
来自 Cambridge English Corpus
Nevertheless, international negotiations over the protection of ozone layer have been remarkably successful.
来自 Cambridge English Corpus
The oxic transition also produced the stratospheric ozone layer, which protects life from the most harmful wavelengths of solar ultraviolet radiation.
来自 Cambridge English Corpus
Ozone diplomacy: new directions in safeguarding the planet.
来自 Cambridge English Corpus
Given the significance of the stratospheric ozone layer, concern regarding the effects of pollution of the stratosphere has been expressed in recent years.
来自 Cambridge English Corpus
The whole appliance is continually vented with forced air to prevent ozone accumulation in the path of the beam.
来自 Cambridge English Corpus
The altitude at which the energy is released will affect the extent of ozone depletion.
来自 Cambridge English Corpus
示例中的观点不代表剑桥词典编辑、剑桥大学出版社和其许可证颁发者的观点。
C1
ozone的翻译
中文(繁体)
臭氧, (尤指海邊的)新鮮空氣…
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ozono, aire puro…
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葡萄牙语
ozônio, ar puro…
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ओझोन, ऑक्सिजनचा एक विषारी प्रकार, स्वच्छ आणि श्वास घेण्यास आनंददायी हवा…
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オゾン…
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ozon, temiz hava, ozon(O3)…
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air marin, ozone…
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ozon…
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ஆக்ஸிஜனின் நச்சு வடிவம், கடலுக்கு அருகில் சுத்தமான மற்றும் சுவாசிக்க இனிமையான காற்று…
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પ્રાણવાયુનો એક ઝેરી પ્રકાર, ઓઝોન, હવા જે ખાસ કરીને સમુદ્રની નજીક…
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frisk (hav-)luft, ozon…
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frisk [havs]luft, ozon…
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udara segar, ozon…
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frische Luft, das Ozon…
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frisk (hav)luft, oson…
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ایک طرح کی زہریلی آکسیجن, سمندر کے قریب کی تازہ ہوا…
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свіже повітря, озон…
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озон…
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ఆక్సిజన్ యొక్క విషపూరిత రూపం, ముఖ్యంగా సముద్రం దగ్గర శుభ్రంగా, పీల్చడానికి ఆహ్లాదకరంగా ఉండే గాలి…
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أوزون…
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ওজোন (অক্সিজেনের একটি বিষাক্ত রূপ), ওজোন (পরিস্রুত বায়ুমণ্ডল যেখানে শ্বাস গ্রহণ আনন্দদায়ক, বিশেষভাবে সমুদ্র নিকটবর্তী এলাকায়)…
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čerstvý mořský vzduch, ozón…
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udara segar, ozon…
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อากาศที่บริสุทธิ์, โอโซนออกซิเจนแบบหนึ่งที่มี 3 อะตอมในหนึ่งโมเลกุล…
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không khí trong lành, một loại oxy…
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오존…
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ozono, (aria pura)…
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Oyster card
oyster mushroom
oystercatcher
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ozone
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ozone更多的中文(简体)翻译
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ozone-friendly
the ozone layer
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“每日一词”
veggie burger
UK
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/ˈvedʒ.i ˌbɜː.ɡər/
US
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/ˈvedʒ.i ˌbɝː.ɡɚ/
a type of food similar to a hamburger but made without meat, by pressing together small pieces of vegetables, seeds, etc. into a flat, round shape
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STM32 调试工具:Segger Ozone - 知乎
STM32 调试工具:Segger Ozone - 知乎首发于机器人控制系统技术切换模式写文章登录/注册STM32 调试工具:Segger Ozone陈鑫 JasonChen康复机器人、外骨骼机器人控制系统研发问题来源因为公司的产品基于程序的可移植性和可维护性考虑,转而使用 C++ 进行程序开发,而不是使用 C。在转写的过程中,调试设备发现使用 KEIL,无法像之前那样直接打断点看变量(一部分变量的信息无法看到,除非是使用全局变量)。这个问题的出现估计是在使用 C++ 时, KEIL 和 JLINK 之间存在适配问题。在通过网络搜索和一系列尝试后,发现 SEGGER 公司提供了 Segger Ozone 这款软件可以使用 JLink 直接打印出来调试信息,非常方便进行开发的调试。因此,在此处介绍软件使用初体验如下。Segger Ozone参考(官方网址):Ozone 是 Segger 公司开发的一个调试工具,用于 Trace 程序的运行。调试初始化配置方法: 打开软件,创建一个新的工程: 2. 选择目标器件: 3. 选择通信方式: 4. 选择链接文件: 5. 给需要调试的位置打上断点:(可以通过 Find in File 查找到你要找的函数) 6. 打开 Terminal 窗口: 7. 配置 Trace: 8. 下载并运行程序: 9. 这样,通过 printf() 函数,在 Terminal 窗口下你就能看到自己需要打印的信息了。 发布于 2020-04-06 12:47STM32嵌入式设计嵌入式开发赞同 104 条评论分享喜欢收藏申请转载文章被以下专栏收录机器人控制系统技术机器人控制系统搭建技
Ozone Layer - Our World in Data
e Layer - Our World in DataOur World in DataBrowse by topicLatestResourcesAboutSubscribeDonateOzone Layerby Hannah Ritchie, Lucas Rodés-Guirao and Max RoserReuse our work freelyCite this researchIntroductionKey InsightsResearch & WritingOther Useful ResourcesChartsEndnotesCite This WorkReuse This WorkThe ozone layer plays a vital role in making the planet habitable for us and other species. High in the atmosphere – between 10 to 50 kilometers above the earth’s surface – the ozone layer absorbs most of the sun’s ultraviolet radiation.
But, during the 1970s, ‘80s, and ‘90s, humans were emitting large quantities of substances that depleted the ozone layer. This led to the creation of ozone holes at the earth’s poles, exposing life to higher levels of ultraviolet radiation and increasing the risks of skin cancer in humans.
During the 1980s, the world came together to form an international agreement to reduce – and eventually eliminate – emissions of these depleting substances. The political agreements were very effective. Since then, global emissions have fallen by more than 99%.
The ozone holes have stopped growing and are now starting to close.
This page includes all of our data, visualizations, and writing on the ozone layer, its depletion, and its path to recovery.
Related topics
Air PollutionEnergyCO₂ and Greenhouse Gas Emissions
Key insights on the Ozone LayerEmissions of substances that deplete the ozone layer have fallen by more than 99%The Montreal Protocol is one of the most successful international agreements to dateIncreasing the ambition of the Montreal Protocol has been essential in protecting the ozone layerThe amount of ozone in the stratosphere was disappearing rapidly but has stabilized since the late 1990sThe ozone hole over the Antarctic grew rapidly until it stopped growing around the year 2000Emissions of substances that deplete the ozone layer have fallen by more than 99%In 1987, the world signed the Montreal Protocol: the first global agreement to reduce the use of substances that deplete the ozone layer, known as ‘ozone-depleting substances.’These are substances such as chlorofluorocarbons (CFCs); hydrochlorofluorocarbons (HFCs); and halon gases used in refrigerators, deodorants, and other industrial processes.Since this agreement entered into force in 1989, global emissions of ozone-depleting substances have fallen by more than 99% as manufacturers have substituted them for less harmful alternatives.This vast decline is shown in the chart.
What you should know about this data
In some years, gasses can have negative consumption values. This occurs when gasses that were produced in previous years get destroyed. If the amount of gas that is destroyed in a given year is larger than the amount that is produced, then the consumption levels will be negative. National statistics can also show negative emissions when gasses are exported.
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The Montreal Protocol is one of the most successful international agreements to dateThe dramatic reduction in the emissions of ozone-depleting substances was only possible through international collaboration and agreements.The Montreal Protocol on Substances that Deplete the Ozone Layer was first agreed upon in 1987 to reduce – and eventually eliminate – the use of man-made ozone-depleting substances to protect the ozone layer.The timeline below the interactive map shows when countries signed the protocol to join this international agreement.The Montreal Protocol was not an instant success in reducing emissions. It has undergone various amendments to increase ambition and reduction targets.But these adjustments have come close to eliminating ozone-depleting substances, making it one of the most successful international agreements of any kind.
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Increasing the ambition of the Montreal Protocol has been essential in protecting the ozone layerInternational agreements been very successful in reducing emissions of ozone-depleting substances. But the initial targets of the Montreal Protocol from 1987 would have been insufficient to tackle the problem.As we see in the visualization, the Montreal Protocol would have slowed emissions of depleting substances compared to a world with no protocol, but it wouldn’t have reduced the amount used.The success came from subsequent revisions, which increased in ambition and reduction targets each time.These projections based on the various revisions are shown in the chart. You can see that the 1992 amendment in Copenhagen was the first not only to slow the increase of emissions but to reduce them.
What you should know about this data
This graphic and data is sourced from the 2018 update report from the Scientific Assessment of Ozone Depletion.1 The report is prepared and updated every four years by the Scientific Assessment Panel (SAP) of the Montreal Protocol on Substances that Deplete the Ozone Layer, formed by the UN Environment Programme in collaboration with the World Meteorological Organization and National Oceanic and Atmospheric Administration (NOAA).
The amount of ozone in the stratosphere was disappearing rapidly but has stabilized since the late 1990sAs a result of human emissions of ozone-depleting substances, concentrations of ozone in the stratosphere – between 10 to 50 kilometers above the earth’s surface – fell rapidly throughout the 1970s, ‘80s, and early ‘90s.This is shown in the chart, where stratospheric ozone concentrations are measured in ‘Dobson units.’Concentrations in the South Hemisphere more than halved from 1979 to 1995.However, as the world reduced its emissions of these depleting gasses, ozone concentrations stabilized from the 1990s. And in recent years, this has slowly started to rebuild again.
What you should know about this data
This data comes from measurements in the Southern Hemisphere, at a latitude of 40°.This data is measured from satellite measurements, which are taken daily. The mean trend shows the average of these daily measurements for any given year. The minimum daily concentration is the lowest concentration recorded on any day across the year.Ozone concentrations are measured in ‘Dobson units’. If you were to take all the ozone in a column of air stretching from the earth’s surface to space, and bring all that ozone to a temperature of 0°C and pressure of one atmosphere, the column would be about 0.3 centimeters thick. Thus, the total ozone would be 0.3 atm-cm. To make the units easier to work with, the “Dobson Unit” is defined to be 0.001 atm-cm. So, our 0.3 atm-cm would be 300 DU.Ozone concentrations, and the ozone hole’s size, are affected by sunlight, temperature, and emissions of depleting substances. This means the size of the hole can vary from year-to-year and vary across the year.
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The ozone hole over the Antarctic grew rapidly until it stopped growing around the year 2000As ozone concentrations in the stratosphere declined throughout the 1970s, ‘80s, and ‘90s, a hole over Antarctica opened up.You can see the first photograph taken of the Antarctic ozone hole in 1985 on the NASA website.We can see the growth of the ozone hole in the chart. By the 1990s, it had expanded to 25 million square kilometers (km2). That’s an area larger than Russia, which has an area of 16 million km2.The ozone hole stopped expanding around the year 2000. This happened because emissions of ozone-depleting substances fell dramatically, and ozone concentrations stopped declining. The ozone hole is now starting to close. But it will take many more decades for it to recover fully.2
What you should know about this data
Ozone concentrations, and the ozone hole’s size, are affected by sunlight, temperature, and emissions of depleting substances. This means the size of the hole can vary from year-to-year and vary across the year.The ozone hole tends to be largest in the Southern Hemisphere Spring – around October.This data is measured from satellite measurements, which are taken daily. The mean trend shows the average of these daily measurements for any given year. The maximum trend is the highest ozone hole area recorded on any day across the year.
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Research & Writing
What is the ozone layer, and why is it so important?
Over the last 50 years, holes in the ozone layer have opened up. Why does that matter for life on Earth?
Hannah Ritchie
Other Useful Resources
How we fixed the ozone layer
by Hannah Ritchie, published at Works in Progress
Images and satellite measurements of the ozone layer
NASA Ozone Watch
Interactive charts on Ozone LayerAntarctic ozone hole areaConcentration of ozone in the stratosphereCountries subscribed to the Montreal ProtocolEmissions of ozone-depleting substancesChange in the consumption of ozone-depleting substancesConsumption of ozone-depleting substancesExcess skin cancer cases due to ozone depletionNumber of parties in multilateral environmental agreementsOzone-depleting substance emissionsStratospheric chlorine concentrations projectionsStratospheric ozone concentration projectionsChart 1 of 11
EndnotesRoss J. Salawitch (Lead Author), David W. Fahey, Michaela I. Hegglin, Laura A. McBride, Walter R. Tribett, Sarah J. Doherty, Twenty Questions and Answers About the Ozone Layer: 2018 Update, Scientific Assessment of Ozone Depletion: 2018, 84 pp., World Meteorological Organization, Geneva, Switzerland, 2019.Strahan, S. E., & Douglass, A. R. (2018). Decline in Antarctic ozone depletion and lower stratospheric chlorine determined from Aura Microwave Limb Sounder observations. Geophysical Research Letters, 45(1), 382-390.
Hegglin, M. I. et al. (2015). Twenty Questions and Answers about the Ozone Layer 2014 Update: Scientific Assessment of Ozone Depletion 2014. World Meteorological Organisation.Cite this workOur articles and data visualizations rely on work from many different people and organizations. When citing this topic page, please also cite the underlying data sources. This topic page can be cited as:Hannah Ritchie, Lucas Rodés-Guirao and Max Roser (2023) - "Ozone Layer". Published online at OurWorldInData.org. Retrieved from: 'https://ourworldindata.org/ozone-layer' [Online Resource]BibTeX citation@article{owidozonelayer,
author = {Hannah Ritchie and Lucas Rodés-Guirao and Max Roser},
title = {Ozone Layer},
journal = {Our World in Data},
year = {2023},
note = {https://ourworldindata.org/ozone-layer}
}Reuse this work freelyAll visualizations, data, and code produced by Our World in Data are completely open access under the Creative Commons BY license. You have the permission to use, distribute, and reproduce these in any medium, provided the source and authors are credited.The data produced by third parties and made available by Our World in Data is subject to the license terms from the original third-party authors. We will always indicate the original source of the data in our documentation, so you should always check the license of any such third-party data before use and redistribution.All of our charts can be embedded in any site.Wordpress Edit PageOur World in Data is free and accessible for everyone.Help us do this work by making a donation.Donate nowAboutContactFeedbackJobsFundingHow to useDonatePrivacy policyLatest workAll chartsTwitterFacebookInstagramThreadsGitHubRSS FeedLicenses: All visualizations, data, and articles produced by Our World in Data are open access under the Creative Commons BY license. You have permission to use, distribute, and reproduce these in any medium, provided the source and authors are credited. All the software and code that we write is open source and made available via GitHub under the permissive MIT license. All other material, including data produced by third parties and made available by Our World in Data, is subject to the license terms from the original third-party authors.Please consult our full legal disclaimer.Our World In Data is a project of the Global Change Data Lab, a registered charity in England and Wales (Charity Number 118643
Spatiotemporal distribution of ground-level ozone in China at a city level | Scientific Reports
Spatiotemporal distribution of ground-level ozone in China at a city level | Scientific Reports
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Spatiotemporal distribution of ground-level ozone in China at a city level
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Published: 29 April 2020
Spatiotemporal distribution of ground-level ozone in China at a city level
Guangfei Yang1, Yuhong Liu1 & Xianneng Li1
Scientific Reports
volume 10, Article number: 7229 (2020)
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AbstractIn recent years, ozone (O3) pollution in China has shown a worsening trend. Due to the vast territory of China, O3 pollution is a widespread and complex problem. It is vital to understand the current spatiotemporal distribution of O3 pollution in China. In this study, we collected hourly data on O3 concentrations in 338 cities from January 1, 2016, to February 28, 2019, to analyze O3 pollution in China from a spatiotemporal perspective. The spatial analysis showed that the O3 concentrations exceeded the limit in seven geographical regions of China to some extent, with more serious pollution in North, East, and Central China. The O3 concentrations in the eastern areas were usually higher than those in the western areas. The temporal analysis showed seasonal variations in O3 concentration, with the highest O3 concentration in the summer and the lowest in the winter. The weekend effect, which occurs in other countries (such as the USA), was found only in some cities in China. We also found that the highest O3 concentration usually occurred in the afternoon and the lowest was in the early morning. The comprehensive analysis in this paper could improve our understanding of the severity of O3 pollution in China.
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IntroductionAir pollution has rapidly increased over the last few decades due to urbanization and industrialization, and this increase has attracted attention around the world, including in China. In 2012, the National Ambient Air Quality Standards (NAAQS) (GB 3095-2012) was published by the Chinese Ministry of Environmental Protection, which identified six environmental pollutants: sulfur dioxide (SO2), nitrogen dioxide (NO2), carbon monoxide (CO), ozone (O3), and particulate matter (PM2.5 and PM10)1,2,3. Several air pollution control policies and programs have been established by the Chinese government4,5,6. However, there is still a gap between China’s ambient air quality and the air quality guidelines (AQG) of the World Health Organization (WHO)7. In recent years, although the concentrations of most pollutants, including NO2, SO2, particulate matter, and CO, decreased in the period of 2013–2016, O3 concentrations have increased by 10.79%8. O3 has become a secondary pollutant after PM2.5, which introduces new challenges to pollution control9.In the past few years, many studies have investigated the impact, formation, and sources of O3 pollution. For instance, Khaniabadi et al.10 found that inhaling high concentrations of O3 or exposure to O3-polluted environments for a long period of time had a negative impact on health. Inhaling high concentrations of O3 can increase the risk of cardiovascular and respiratory diseases, which contribute to the overall mortality rate. Huang et al.11 found that ambient O3 exposure was related to the tremendous disease burden of chronic obstructive pulmonary disease in Ningbo, China, and the elderly comprised a more susceptible population. Existing evidence also reveals the adverse effects of O3 on mental health12. O3 pollution will not only have a negative impact on human health13 but also have a variety of adverse effects on plants, such as declines in crop yields and quality14,15,16. Because O3 has a negative impact on the transfer of nitrogen to grain, O3 pollution will reduce the fertilizer efficiency of wheat17, leading to the inhibition of net photosynthesis of wheat18. Additionally, O3 is a secondary pollutant that is formed by other pollutants through reactions19,20,21. Therefore, the formation of O3 pollution is affected by many factors22,23,24. Studies have shown that volatile organic compounds (VOCs) and NOx are key precursors of O3 formation23. Aromatic hydrocarbons and olefins are considered the main contributors to O3 formation in many cities or regions in China. Ethylene, trans-pentene, propene, and BTEX (benzene, ethylbenzene, toluene, m-, p-, and o-xylene), as well as warm weather and low wind speeds, are also major contributors to O3 formation25. Given that China is currently plagued by complex O3 pollution problems, understanding the spatiotemporal pattern of O3 pollution in China is of great significance for conducting environmental epidemiological studies and drafting appropriate regional O3 pollution control strategies.Some scholars have launched investigations on the spatiotemporal pattern of O3. In Nanjing, a unimodal peak was observed with the highest O3 levels occurring from 14:00 to 15:00, and the O3 concentration reached its maximum and minimum levels in the summer and winter, respectively3. Wang et al.26 studied the ground-level O3 concentrations of 6 major Chinese cities located on both sides of the Heihe-Tengchong line, and they found that ground-level O3 concentrations exhibited monthly variability, peaking in summer and reaching the lowest levels in winter. The diurnal cycle reached a minimum in the morning and peaked in the afternoon. Some research has found that the O3 distribution pattern is also related to terrain features9,27.As previously mentioned, most of the studies on O3 spatiotemporal patterns are carried out with a short time scale and low spatial resolution and generally focus on a specific city or a limited spatial region. To the best of our knowledge, there has been a lack of research on the spatiotemporal pattern of O3 in China using a higher spatial resolution and long time-series datasets. Recently, China established a large-scale ground real-time air quality monitoring network, which provides data we can use to conduct research on the spatiotemporal distribution pattern of O3 pollution nationwide.In brief, this research makes the following contributions. First, we obtained the O3 concentration data of 338 cities across China for more than three years, covering 1-Jan-2016 to 28-Feb-2019. In terms of spatial perspective, we investigated the O3 concentrations in seven major geographic regions and three major urban agglomerations to conduct a more in-depth analysis and discussion. In terms of temporal perspective, we studied the annual, seasonal, monthly, weekly, daily, and diurnal and nocturnal variations in the O3 concentrations. Second, the reasons for different patterns in different regions were briefly analyzed. The research results from this large dataset can not only help us elaborate on the spatiotemporal distribution pattern of O3 concentration in China with a better spatiotemporal resolution and increase public awareness of the current O3 pollution situation in China but also assist the relevant departments in formulating more targeted O3 pollution prevention and control policies to meet the NAAQS and even the AQG standards in the future.Results and DiscussionThe NAAQS and the WHO set concentration limits for the maximum daily 8-hour average (MDA8) O3 concentration. Two levels of limits are specified in the NAAQS (Grade 1 and Grade 2), and three levels of limits are specified in the WHO standard (AQG, Interim target 1 and High level) (see Table 1).Table 1 The O3 concentration limits of the NAAQS in China and the WHO (unit: μg/m3).Full size tableSpatial distribution of O3 in ChinaFigure 1 shows the spatial distributions of the O3 concentrations in 338 cities in China in 2016–2018. The regions with the most O3 pollution were mainly concentrated in North China and Central China, especially in the Beijing-Tianjin-Hebei region (BTH) region. In addition, the O3 pollution in the Chengdu-Chongqing and the Pearl River Delta region (PRD) regions was significantly higher than that of their neighboring regions. O3 pollution in China has shown a trend of outward expansion. As shown in Table 2, based on the statistical results of the 90th percentile of the maximum daily 8-hour average urban O3 concentration, the top 10 cities with severe O3 pollution are mainly located in North China, Central China and the East China.Figure 1The spatial distribution of the 90th percentile of the maximum daily 8-hour average of the urban O3 concentration in 338 cities in China in 2016 (a), 2017 (b), and 2018 (c). The maps were generated in ArcGIS10.2, URL: http://www.esrichina-bj.cn/softwareproduct/ArcGIS/.Full size imageTable 2 The top 10 cities with the highest 90th percentile of the maximum daily 8-hour average urban O3 concentration in 2016-2018 in China.Full size tableFig. 2 displays the over-standard rate of the O3 concentration in seven geographical regions in China. None of the cities in North China met the AQG or Grade 1 limit, and nearly 70% exceeded the Grade 2 limit. In East and Central China, nearly 40% of urban O3 concentrations exceeded the Grade 2 limit. The O3 pollution in other regions was not so prominent; however, there were still considerable gaps from the AQG standard.Figure 2The over-standard rate of O3 concentration in 338 Chinese cities. The results of the seven geographical regions are also displayed.Full size imageO3 is a secondary pollutant, which is generally formed in the atmosphere through photochemical pathways of NOx and volatile organic compounds (VOCs)28,29,30,31,32. Most of the NOx and VOCs come from heavy industries, such as coal-fired power plants, the steel industry, and the cement industry. Some studies found that the local photochemical reaction process has made an important contribution to the formation of O333, including the consumption of NO2 during the photochemical reaction process23, which has been observed in regions such as North China and Yangtze River Delta (YRD) region34,35.Additionally, PM pollution control in these regions has achieved certain results, and the reduction in haze has led to increased visibility, which in turn, has promoted the process of photochemical reactions and promoted the formation of O3 pollution. It is worth noting that some cities in western China, where industrial activities are infrequent, sometimes have high concentrations of O3. In these high-altitude regions, the increase in O3 concentration may be related to the transport of O3 from the stratosphere to the troposphere36. In addition, meteorological environments with a high ultraviolet intensity and low humidity are conducive to O3 formation. In general, the formation of O3 pollution is affected by many factors, including prerequisite pollutant concentrations and meteorological conditions.Annual variation in O3 in ChinaFigure 3 shows the change in ozone concentration in all cities in China in 2016-2018. The top and bottom whiskers extend from the hinges to the largest values by no more than 1.5* IQR (interquartile range). The upper and lower bounds of the box represent the 75th and 25th quartiles, respectively. The line in the middle of the box represents the median. The cross points indicate the mean values, and the square points outside the whisker indicate outliers. From 2016 to 2018, the O3 concentration showed an upward trend, and the ozone levels were roughly the same in 2017 and 2018. Figure 1 shows that the scope of heavy O3 pollution has gradually expanded. This phenomenon is also depicted in Fig. 4. In 2016, more than 95% of cities failed to meet the Grade 1 standard, and nearly 20% failed to meet the Grade 2 standard. In 2017 and 2018, these values increased to 99% and 30%, respectively.Figure 3The box plots of the annual O3 concentrations of 338 cities in China in 2016–2018.Full size imageFigure 4The annual over-standard rate of the O3 concentrations in 338 Chinese cities in 2016-2018.Full size imageSeasonal variation in O3 in ChinaThe distributions of O3 in different seasons were heterogeneous, exhibiting significant seasonal variations. In general, O3 pollution in the summer is significantly higher than that in winter (Fig. 5). Because the photochemical reaction process is affected by meteorological conditions such as light and temperature, the meteorological conditions in summer are more suitable for photochemical reactions. In contrast, the UV intensity in winter is low, and the photochemical reaction is not enough to form heavy O3 pollution.Figure 5The average O3 concentrations of the 338 cities of China during 2016, 2017 and 2018 (a) and during spring (b), summer (c), autumn (d), and winter (e). The maps were generated in ArcGIS10.2, URL: http://www.esrichina-bj.cn/softwareproduct/ArcGIS/.Full size imageSeasonality is also reflected in spatial variation. In the spring and summer, O3 pollution is highest in North, East, and Central China. In autumn, O3 pollution gradually shifts to the south. In winter, national O3 pollution is relatively mild, and only a small part of South China suffers from O3 pollution. Overall, the problem of O3 pollution in the eastern areas is more serious than that in the western areas. The seasonality of O3 concentration changes in the BTH region and the YRD region is relatively high. However, the seasonality of O3 concentration changes in the PRD region is not as obvious. In the BTH region and the YRD region, the maximum and minimum O3 concentrations were observed in the summer and winter, respectively. In the PRD region, the maximum O3 concentration was observed in autumn, and the minimum was observed in winter.The formation of O3 pollution varies based on factors such as the overall NOx and VOC emissions37,38,39, topography40, and atmospheric circulation in the region31,41. Evidence suggests that the high O3 pollution in the BTH region may be related to the emissions of precursor pollutants and the transportation of VOCs in neighboring provinces42,43. In the YRD region, the high temperatures in summer and the lower humidity can easily induce O3 pollution. The O3 concentration in the PRD region throughout the year is close and at a high level because the temperature throughout the year is similar and the annual average temperature exceeds 20°C in this region.Monthly variation in O3 in ChinaFigure 6 illustrates the highest maximum, upper-quartile, median, lower-quartile, and minimum values of the monthly variations in O3 concentration from January to December in the seven regions and the total for all cities. The data confirm that the O3 concentration changes periodically depending on the month. Except for South and Southwest China, the trends in the O3 concentration variations in other regions are consistent with the national trend, showing an inverted V-shaped curve. The O3 concentration gradually increases from January to June, reaching the highest value in June, and then gradually decreases from June to December. The trend of O3 concentration variations in South China and Southwest China is relatively stable. The variation in the O3 concentration in South China shows an M-shaped curve, and the O3 concentration is higher in May and October. O3 pollution in Southwest China is “coming early and going fast”. The O3 concentration peaks around May and then falls sharply starting in June.Figure 6Monthly variation in the maximum daily 8-hour average concentration of O3 in seven geographical regions and in all cities during 2016-2018.Full size imageThe monthly pattern of O3 can be attributed to changes in meteorological conditions and seasonal variations in precursor emissions. The decrease in the O3 concentration in South China in summer may be attributed to the climatic characteristic of the southwest monsoon that prevails in summer. The change in the O3 concentration in Southwest China is strongly affected by ultraviolet radiation. In addition, the penetration of stratospheric ozone into the troposphere is another reason supporting the high O3 concentration in the region.Weekly variation in O3 in ChinaThe weekly variation in the O3 concentration is shown in Fig. 7. The trends in different regions are not the same, but in general, they follow a W-shape. In North, Central, South, and Southwest China and in the BTH and PRD regions, the O3 concentration showed a valley on Tuesday. In North China, the YRD region, and the BTH region, the O3 concentration showed another valley on Saturday. Some scholars have studied the weekend effect of O3 that was first reported in New York in 1974, which suggested that the O3 concentration was higher during the weekend than on weekdays44. The weekend effect has been investigated in many other cities in the United States45,46,47, Europe48,49,50, and Asia51,52,53. The weekend effect of urban O3 is related to the decrease in human activities.Figure 7Weekly variation in the maximum daily 8-hour average concentration of O3 in seven geographical regions and three urban agglomerations in China during 2016-2018.Full size imageAs shown in Fig. 8, the weekly variation in O3 concentration varies greatly in different regions and seasons. In our study, the valley value of O3 concentration often occurs on Tuesday. The weekend effect of O3 is more evident in the Northeast China, South China, Central China in summer, and Northwest China, Southwest China in winter to a certain degree. However, the general weekend effect of O3 pollution is not significant, from a national scale. The weekly variation in O3 concentration is affected by complex factors, the most likely of which is characteristics of urban resident activities. At present, no natural process has been found to produce climate change with a cycle of about 7 days, so Dominique et al.54 believe that the existence of such a cyclic process is manifestation of human impact on climate. Due to the obvious weekly cycle of human activities, many meteorological elements in many regions have corresponding weekly cycle characteristics55. Meteorological elements of some cities have been observed to have varying degrees of weekly cycle characteristics, such as temperature56,57, precipitation frequency58,59, etc., which have a significant cycle with 7-day. The change of these climate factors will further affect the generation of O3 in the photochemical reaction process, and thus affect the weekly variation. In general, the weekly variations in O3 concentration are not very prominent, which shows that the weekly changes in human activities have limited effects on O3 concentration.Figure 8Weekly variation in the maximum daily 8-hour average concentration of O3 during four seasons in seven geographical regions during 2016-2018.Full size imageDaily variation in O3 in ChinaFigure 9 shows the daily O3 concentration from January 1, 2016, to December 31, 2018. As shown in the figure, the daily variation in the O3 concentration is usually continuous. The change from high concentration to low concentration, or from low concentration to high concentration, is often a gradual process rather than a sudden change. In most parts of the country, the daily variation of O3 concentration shows an inverse U-shaped trend during each year, i.e., gradually increasing first and then decreasing. Except for South China, including the Pearl River Delta, the daily variation process of O3 concentration has volatility. When observing horizontally from three years, the three cycles of O3 variation can be clearly distinguished. We also found that for at least 1/3 of the days in the three years in each region, the O3 concentration exceeded the AQG, while for more than 1/3 of the days in North China, the O3 concentration exceeded Grade 1 of the NAAQS. When observing vertically, during the days with O3 pollution, the BTH, YRD, and PRD regions usually had even higher O3 concentrations than their neighboring areas. In short, the figure simultaneously shows the seasonal variation pattern as well as the spatial distribution characteristic of O3 concentration.Figure 9Daily variation in the maximum daily 8-hour average concentration of O3 in seven geographical regions and three urban agglomerations during 2016-2018. (This figure was created by using matplotlib, a Python 2D plotting library, URL:https://matplotlib.org).Full size imageDiurnal and nocturnal variation in O3 in ChinaThe hourly data on O3 concentration are shown in Fig. 10 and were used to investigate the diurnal and nocturnal variations in O3 pollutants in seven regions and three urban agglomerations in China. All regions showed a similar overall trend of O3 concentration, with a single peak. The O3 concentration was relatively lower at night, but as the sun rose, the O3 concentration gradually increased. The peak appeared between 14:00 and 16:00 (i.e., in the afternoon). After 16:00, the O3 concentration gradually decreased. The change in O3 concentration was affected by the temperature, solar radiation intensity, and various emissions from the surrounding environment. At night, due to the absence of solar radiation and the precursor of the photochemical reaction, the reaction was weakened and the O3 concentration decreased.Figure 10Diurnal and nocturnal variation in the average hourly concentration of O3 in seven geographical regions and three urban agglomerations during 2016-2018.Full size imageThere are still some differences in the diurnal and nocturnal variations in the O3 concentration in various regions. For example, the variations in Southwest and Northwest China have a hysteresis phenomenon relative to other regions. The phenomenon is attributed to China’s vast territory, with more than 60° of east-west longitude, spanning 5,200 km and five time zones. Although Beijing time is uniformly used in China, there are actually time differences between the eastern and western regions.O3-NOx-VOC sensitivity regimes and influencing factorsO3 is a secondary pollutant, and it is mainly produced by a series of photochemical reactions among precursors. Therefore, the formation of O3 pollution is affected by many factors in addition to meteorological factors. The most important factors are its precursors NOx and VOCs. The relationship between O3 and its precursor concentrations is generally nonlinear60. The decrease in precursor concentration does not necessarily result in a corresponding decrease in O3 concentration, and the sensitivity of O3 to NOx and VOCs will be different under different environmental conditions in the same region. The O3-NOx-VOC sensitivity regimes can describe the relationship between O3 and its local precursors (NOX and VOCs). The sensitivity relationship between O3 and its precursors determines the controlled types of O3 pollution in different regions. In brief, when the concentration of NOx in the atmosphere is high, the generation of O3 is controlled by VOCs; however, when the VOC concentration in the atmosphere is high, O3 generation is controlled by NOx. For example, in VOC-sensitive areas, the O3 concentration may increase with the reduction of the NOx concentration23. Clarifying whether O3 generation in a region is VOC-sensitive or NOx-sensitive is one of the important issues related to O3 generation mechanisms, which will be helpful in determining the control of targeted emissions to reduce O3 pollution61 and formulating O3 pollution control strategies.In this paper, we summarize the O3-NOx-VOC sensitivity regimes in major cities in China that have been studied, and the results are shown in Supplementary Table S1. In the urban districts of most cities, including Beijing, Tianjin, Shanghai and Guangzhou, O3 generation is VOC-sensitive, mainly because human intervention in urban districts has greatly affected the emissions of precursors. Industry and transportation caused a large amount of NOx emissions, and the titration effect suppressed the increase in the O3 concentration in urban areas. In these areas, the priority control of VOC emissions is more helpful in controlling local O3 pollution. However, in the suburban areas of some cities, such as Lanzhou, Guiyang, Chongqing, and Xuzhou, the generation of O3 is NOx-sensitive. The suburbs are less affected by anthropogenic emissions, and the migration of pollutants caused by the wind will affect O3 pollution in the suburbs. In these areas, to suppress O3 generation more effectively, priority should be given to the control of NOx emissions.In addition, the meteorological influencing factors in major cities in China are provided in Supplementary Table S1. The main meteorological factors that affect O3 generation include temperature, relative humidity, wind speed, wind direction, solar radiation, atmospheric pressure, cloud cover, sunshine duration, precipitation, ultraviolet radiation, visibility, and geopotential height. The statistics of their frequency are shown in Supplementary Fig. S1. In different regions, meteorological factors have heterogeneous effects on O3 generation. In general, O3 has a significant correlation with temperature and relative humidity. High temperature and low relative humidity are more conducive to the formation of O3, while meteorological factors such as sunshine duration, wind direction and wind speed have a crucial impact on the changes in O3 concentration.Combined with the results of previous statistical analyses, we found that the O3 pollution affecting other cities is often caused by the synergistic effects of precursors and meteorological factors. For example, MDA8 in Beijing and its surrounding areas mainly occur at conditions of high temperature, low cloud cover, low relative humidity, weak southeast wind, low planetary boundary layer height, and the presence of a large amount of NOx and VOCs62. In Taiyuan, when the wind direction is southerly or southwesterly, the concentration of O3 is higher, which indicates that the increase in O3 concentration in Taiyuan is not only related to the local generation but also related to the external transport from the south63,64. The O3 volume fraction and its generation rate in Langfang showed a significant positive correlation with air temperature and a significant negative correlation with total cloud cover. It is also susceptible to transmission in the southern region of Hebei and Tianjin.From a long-term perspective, according to the characteristics of different O3 pollution in different regions, priority should be given to strengthen the coordinated control of the sensitive precursor emissions in the region. Forecasting in advance when meteorological conditions are adverse and taking timely NOx and VOC control measures are important ways to solve regional O3 pollution problems.ConclusionsThis study analyzed the spatiotemporal distributions of O3 concentrations in 338 prefecture-level cities in China from January 2016 to February 2019. The purpose was to understand the current status of O3 pollution in China with a higher spatial resolution and a longer time series. Our study has the following findings:O3 had obvious spatial heterogeneity. Only a few cities met the AQG standard of the WHO. O3 pollution in North, East, and Central China was more serious, especially in the BTH region. The O3 concentrations in the BTH, YRD, and PRD regions were usually higher than those in their neighboring cities. In the spring and summer, O3 pollution in the north was more serious; in autumn, O3 pollution shifted toward the south. In winter, the O3 pollution problem was relatively mild across China.O3 showed a significant temporal variation pattern. The O3 concentration increased each year from 2016 to 2018. For the monthly variation in O3, except for South and Southwest China, other regions showed an inverted-V curve. Although the weekly variation in O3 concentration was not exactly the same in different areas, some cities showed a W-shape. The O3 concentration was lower on Tuesday and Saturday, and no obvious weekend effect was found. The study also characterized the diurnal and nocturnal variation pattern of O3 concentration. The O3 concentration was significantly higher during the day because of factors such as solar radiation, temperature, and precursor emissions. Due to the different time zones in different cities, the western region had a remarkable lag effect compared with the eastern region.At present, China has made some achievements in the control of PM, NOx and other pollutants; however, the problem of O3 pollution has become increasingly prominent. Against the background of China’s severe composite air pollution, the need for the coordinated control of multiple pollutants is becoming increasingly apparent. According to our understanding, there is coexistence of VOC control and NOx control in China’s O3 pollution, and the reduction of particulate matter pollution has exacerbated the problem of O3 pollution in China. The government should strengthen the monitoring of VOCs and combine the characteristics of O3 pollution in different regions to formulate more targeted O3 pollution control strategies to achieve a win-win situation of haze governance and O3 control.Data and methodsThe regional division of ChinaA total of 338 cities, including prefecture-level cities and municipalities, are used as basic study units to investigate the spatial and temporal distribution of O3 in China. To analyze the results more clearly, China was divided into seven geographical regions: Northeast China (NEC), North China (NC), East China (EC), Central China (CC), South China (SC), Northwest China (NWC), and Southwest China (SWC), and three urban agglomerations: Beijing-Tianjin-Hebei region (BTH), the Yangtze River Delta region (YRD), and the Pearl River Delta region (PRD) (Fig. 11).Figure 11The regional division of China into seven geographical regions and three urban agglomerations. The map was generated in ArcGIS10.2, URL: http://www.esrichina-bj.cn/softwareproduct/ArcGIS/.Full size imageGround-level O3 monitoring dataThe China National Environmental Monitoring Center (CNEMC) continuously operates and maintains the national air quality monitoring network of China. The network has comprised 496 stations in 74 cities since 2012, and the network was extended to 1436 monitoring stations in 338 cities after 2016. The real-time concentration of O3 was measured by the ultraviolet absorption spectrometry method and differential optical absorption spectroscopy at each monitoring site. The instrumental operation, maintenance, data assurance and quality control were properly conducted based on the most recent revisions of China Environmental Protection Standards2. The real-time hourly O3 concentration data are continuously recorded by the CNEMC in China and are provided to the public. The data for this study were obtained during the period from 1-Jan-2016 to 28-Feb-2019.Maximum daily 8-hour average O3 and the annual average O3 concentrationIn view of the impact of long-term O3 exposure on animals and plants, limits of the maximum daily 8-hour average O3 concentration are specified in the NAAQS. Therefore, the average hourly O3 concentration is calculated every 8 hours, which should include at least 6 hourly values within a given 8-hour period; otherwise, the average value is considered to be invalid. Invalid values are not accepted in subsequent analysis. Finally, the maximum daily 8-hour average O3 concentration in a day is used to represent the O3 level of that day. Additionally, the ‘technical regulation for ambient air quality assessment of China’ (on trial) (HJ 633-2013) published by the Ministry of Ecology and Environment of China (MEE) determined that the O3 annual assessment standard for a city is equal to the 90th percentile of MDA8.Statistical methodThe spatial distribution of O3 is analyzed by calculating the average MDA8 data of all cities in each region. The annual, seasonal, monthly, weekly and daily variations in O3 are represented by the average of the MDA8 of each city. Diurnal and nocturnal O3 variation is calculated using the hourly O3 concentration of each city.
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Download referencesAcknowledgementsThis work is supported by the National Natural Science Foundation of China (71671024, 71601028, 71421001), Fundamental Research Funds for the Central Universities (DUT20JC38, DUT20RW301), Humanity and Social Science Foundation of the Ministry of Education of China (15YJCZH198), Social Planning Foundation of Liaoning (L17AGL012), and Scientific and Technological Innovation Foundation of Dalian (2018J11CY009). The authors would like to thank the reviewers for their constructive comments.Author informationAuthors and AffiliationsInstitute of Systems Engineering, Dalian University of Technology, Dalian, ChinaGuangfei Yang, Yuhong Liu & Xianneng LiAuthorsGuangfei YangView author publicationsYou can also search for this author in
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PubMed Google ScholarContributionsG.F.Y. and Y.H.L. designed and performed the research. G.F.Y. and Y.H.L. wrote the manuscript and checked the Analysis. X.N.L. reviewed the analysis and revised the manuscript.Corresponding authorCorrespondence to
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Reprints and permissionsAbout this articleCite this articleYang, G., Liu, Y. & Li, X. Spatiotemporal distribution of ground-level ozone in China at a city level.
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The two faces of ozone
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In the upper atmosphere, ozone is essential to protect the planet through absorption of ultraviolet radiation; but at ground level, ozone is a pollutant, and increasing anthropogenic emissions are resulting in higher levels. Reducing emissions would mitigate the harmful effects of ozone as well as potentially increasing a natural carbon sink.
Ozone is probably most associated with its high abundance in the Earth’s upper atmosphere. The ozone layer in the stratosphere absorbs much of the incoming solar ultraviolet radiation and came into the wider general consciousness in the 1980s with the discovery that it was seasonally thinning. This led to the 1987 Montreal Protocol on Substances that Deplete the Ozone Layer, an example of a successful international environmental protection agreement. The phase-out of chlorofluorocarbons and halons, through the transition and eventual phase-out of less ozone-damaging substances such as hydrofluorocarbons, has seen declines in their emissions, with stabilization and now ongoing recovery of the ozone layer. These ozone-depleting substances (ODS) are themselves potent greenhouse gases and, with their atmospheric lifespan of 50–100 years, have contributed to global warming, but to what extent? In a Letter in this issue, Lorenzo Polvani and co-authors investigate the role that these ODS have played in Arctic warming from 1955 to 2015. The model results show that a substantial fraction, almost 0.8 °C of the Arctic surface warming and nearly 0.7 × 106 km2 loss of sea ice, has been caused by ODS. Removal of these emissions by the Montreal Protocol has in fact helped to mitigate a warming gas, meaning that the protocol has had a role not only in helping to restore the ozone layer, but also in climate action, with warming approximately a third smaller owing to the absence of increasing ODS.
Credit: Shay Levy / Alamy Stock PhotoMoving closer to Earth, ozone is a pollutant. Formed by the reaction of sunlight with anthropogenic emissions of carbon monoxide, volatile organic compounds, methane and nitrogen oxides, it can present a respiratory health risk and has a damaging effect on crops and ecosystems.As the climate changes, ozone is just one factor influencing vegetation. Understanding its interactions with other factors — such as CO2 changes, temperature and precipitation, nutrient availability and pollination efficiency as well as distributions of microbial and insect species — is important to predict and prepare for impacts on food production and ecosystem services. Exposure to ozone is predicted to increase under a high emissions scenario for all major biomes, and even under RCP4.5 there is increased exposure for 50% of terrestrial ecosystems (Fuhrer, J. et al. Ecol. Evol. 6, 8785–8799; 2016).Crop response to ozone is varied, with wheat typically seeing a decline in harvest yields, and overall crop yields are predicted to decline by about 10% by 2050; impacts of ozone can include changes in cellular carbon allocation, visible injury and reduced photosynthesis (L. D. Emberson et al. Eur. J. Agron. 100, 19–34; 2018). Although there is limited evidence for fruits, nuts and seeds, the available data on these yield impacts show that ozone and temperature have a consistently negative effect (C. Alae-Carew et al. Environ. Res. Lett. https://doi.org/10.1088/1748-9326/ab5cc0; 2019). Understanding regional pollution levels and the effects of ozone is important to ensure food and nutritional security into the future.As emissions continue to cause increases in ground-level ozone, reductions in emissions are needed to decrease this pollutant, but natural reactive halogens (chlorine, bromine and iodine species) already act to partially reduce the ozone burden. Natural halogens are primarily released from the ocean, from phytoplankton and algae and from abiotic sources. How these processes will change in the future is considered in an Article in this issue by Fernando Iglesias-Suarez and colleagues. Currently, halogens deplete around 13% of lower-atmosphere ozone, and this value is predicted to stay constant into the future, as increasing halogen levels are offset by regional differences in ozone distribution and loss.Reducing emissions would also reduce ozone damage to vegetation, which would enhance the land carbon sink. In their Letter in this issue, Nadine Unger and collaborators consider the benefits to gross primary productivity, or photosynthesis, of a 50% cut in emissions from the seven sectors that are the largest sources of anthropogenic ozone precursors. Emissions reductions in road transport and the energy sector would have the most impact in eastern China, the eastern United States, Europe and globally, highlighting that mitigating ozone vegetation damage would not only benefit food security and health but also enhance a carbon sink.Cutting ODS emissions has worked to protect the ozone layer, with the added benefit that removing the increasing atmospheric concentration of those potent greenhouse gases has avoided additional warming. Ozone can be a less-discussed by-product of antrhopogenic emissions, but the benefit of reducing emissions to minimize its polluting effects on health and vegetation could be substantial.
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Nat. Clim. Chang. 10, 97 (2020). https://doi.org/10.1038/s41558-020-0704-5Download citationPublished: 31 January 2020Issue Date: February 2020DOI: https://doi.org/10.1038/s41558-020-0704-5Share this articleAnyone you share the following link with will be able to read this content:Get shareable linkSorry, a shareable link is not currently available for this article.Copy to clipboard
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